H2可以作为o-H2和p-H2的混合物处理吗? —兼释H2的残余熵

本文阐述了H_2不能作为正氢和仲氢的混合物处理的理由,提出了从光谱熵的定义出发解释H_2的残余熵的方法。     

长贮过程中发动机HTPB推进剂老化机理分析

为揭示固体推进剂在长期贮存过程中的老化机理,解剖了自然贮存19年贴壁浇注的端羟基聚丁二烯橡胶推进剂装药发动机,沿着药柱径向不同位置进行了取样,并采用扫描电镜、能量色散X射线光谱仪、红外吸收光谱、交联密度等多种手段对这些样品进行了测试分析。研究发现：贴壁浇注发动机药柱不同位置推进剂的老化程度不尽相同,越靠近非金属壳体位置,推进剂的老化程度越严重。进一步深入分析表明：除了丁羟胶中双键的氧化断链和端羟基的缩合等影响推进剂老化,铝粉氧化产生的铝离子会催化丁羟胶双键与氯气或水发生加成反应生成■双键和仲醇,而铝离子迁移和分布的不均匀会引起药柱老化的不均匀性。研究结果对推进剂配方设计和防老化措施的研究具有重要意义。     

A new experimental way for the monitoring of the real/equivalent in-service-time of double base rocket propellant by coupling VST and PCA

The assessment of the real in-service-time(RIST)and the equivalent in-service-time(EIST)of double base rocket propellants(DBRPs)is of utmost importance for the safe storage and use of weapon systems as well as the efficiency of the accelerated aging plans.In this work,four DBRPs with similar chemical composition and different natural aging have been artificially aged at T = 338.65 K for 4 months with sampling every 30 days.The unaged and artificially aged samples have been investigated by vacuum stability test(VST)at five isothermal temperatures(T = 333.15 K,343.15 K,353.15 K,363.15 K,and 373.15 K).The volume of the evolved gases in VST was found to decrease with natural/artificial aging.Furthermore,the VST data were treated and subjected to principal component analysis(PCA).The results showed excellent discrimination of the DBRP samples according to their stability thermal properties.Most of the variance was described by the first principal component(PC1)whose scores were linearly correlated with the natural aging durations when PCA is applied on VST data obtained at T = 363.15 K.In light of the obtained results,a new experimental way for the estimation of the real/equivalent IST was proposed,which takes into account the impact of the natural aging of the sample.The approach predicts successfully the RIST of two similar DBRPs with a relative deviation of less than 2％.At the specific heating temperature T = 338.65 K,the developed model provides more conceivable EIST values,with asymptotic behavior against artificial aging duration evolution,thus overcoming some shortcomings of the common generalized van't Hoff formula(GvH).     

耐海水高耐候丙烯酸树脂的合成及面漆性能分析

为合成耐海水与高耐候的丙烯酸树脂,选择甲基丙烯酸甲酯、甲基丙烯酸羟丁酯、丙烯酸异辛酯和丙烯酸已内酯,经引发剂作用,采用同步滴加法进行聚合反应,通过调节温度并测定酸价控制反应历程,并将合成的不同玻璃化温度的丙烯酸树脂配制成具有适当玻璃化温度梯度的耐海水面漆成膜树脂体系。选择HDT-90固化剂与丙烯酸成膜树脂作用,制备耐海水面漆涂层样品。性能测试结果表明,研制的耐海水面漆具有优良的耐候性和抗老化性。     

Study of simple plane wave generator with an air-metal barrier

Plane wave generators (PWGs) are used to accelerate flyer plates to high velocities with their generated plane waves, which are widely used in the test of dynamic properties of materials. The traditional PWG is composed of two explosives with different detonation velocities. It is difficult to implement the related fabrication processes and control the generated waves due to its complicated structures. A simple plane wave generator is presented in this paper, which is composed of two identical cylindrical high explosive (HE) charges and an air-metal barrier. A theoretical model was established based on two different paths of the propagation of detonation waves, based on which the size of air-metal barrier was calculated for a given charge. The corresponding numerical simulations were also carried out by AUTODYN-2D^® based on the calculated results, which were used to compare with the theoretical calculations. A detonation wave with a flatness of 0.039 μs within the range of 70-percent diameter of the main charge was obtained through the simulations.     

Numerical simulation of base flow with hot base bleed for two jet models

In order to improve the benefits of base bleed in base flow field, the base flow with hot base bleed for two jet models is studied. Two-dimensional axisymmetric Navier–Stokes equations are computed by using a finite volume scheme. The base flow of a cylinder afterbody with base bleed is simulated. The simulation results are validated with the experimental data, and the experimental results are well reproduced. On this basis, the base flow fields with base bleed for a circular jet model and an annulus jet model are investigated by selecting the injection temperature from 830 K to 2200 K. The results show that the base pressure of the annular jet model is higher than that of the circular jet model with the changes of the injection parameter and the injection temperature. For the circular jet model, the hot gases are concentrated in the vicinity of the base. For the annular jet model, the bleed gases flow into the shear layer directly so that the hot gases are concentrated in the shear layer. The latter temperature distribution is better for the increase of base pressure.     

氦原子1S, 3S, 1P, 3P态的电子关联计算

本文从二次量子化公式出发,选取广义Laguerre多项式乘以γ~lcxp(-alγ)作为单电子径向函数完全集,这里a_l是依赖于轨道角动量l的变分参数,用组态相互作用方法计算了氨原子~1S,~3S,~1P,~3P态的能量和波函数。当组态限于主量子数n≤4,计算的能量相对精度约为99.9%;当组态限于%≤6,能量相对精度约为99.99%;而Hartree Fock方法的能量相对精度约为99%,利用原子波函数计算了一些原子参数,其结果与其他作者的结果符合很好。     

多孔材料药型罩聚能射流的形成条件

依据Herrmann状态方程和斜冲击波关系估算了多孔材料药型罩压垮之前的冲击温升,求解了经过冲击压缩卸载后材料的声速。给出了多孔材料药型罩聚能射流的形成条件。初始冲击温升会使材料的声速和强度降低,从而使多孔材料聚能射流形成射流的高速和低速条件降低。     

Transverse relaxation characteristic and stress relaxation model considering molecular chains of HTPB coating based on pre-strained thermal aging

In order to accurately describe the transverse relaxation characteristic and stress relaxation modulus of HTPB coating during pre-strain thermal aging process, a one month thermal aging test was carried out at 70 C with pre-strain of 0％, 3％, 6％ and 9％, respectively. The low-field 1H NMR and stress relaxation modulus tests were carried out for HTPB coating at different aging stages. The stress relaxation model considering the molecular chains was proposed according to the changes of crosslinking chain and dangling chain of HTPB coating during pre-strain aging. The results showed that with the increase of aging time, the decay rate of transverse relaxation curve became faster, the transverse relaxation time decreased, the value of combined parameter qMrl increased, the proportion of crosslinking chain decreased, while the proportion of dangling chain increased. Moreover, the stress relaxation modulus increased, the crosslinking network structure of HTPB coating became denser and the degree of cross-linking increased. At the initial aging stage, the pre-strain will destroy the crosslinking network structure of HTPB coating to a certain extent. With the increase of aging time, the effect of pre-strain will gradually weaken and the influence of aging on materials will gradually increase. The correlations between the stress relaxation model considering the molecular chains and the test results were more than 0.9950, which can accurately describe the stress relaxation modulus of HTPB coating during the pre-strain thermal aging process.     

弹性压杆稳定性的一般表达式

本文推导出等截面弹性压杆稳定性的一般表达式。17种在各种边界条件下的弹性压杆的临界压力计算公式均是它的特殊情况。